Plain carbon steels are widely utilized in various industrial applications primarily due to their low cost. However, these steels often fall short in terms of mechanical properties and wear resistance. The deposition of hard and wear-resistant coatings on these steels significantly enhances their performance and extends their range of applications. Colomonoy 6, is a nickel-based superalloy, enhance hardness, erosion resistance, wear resistance, and corrosion resistance on the applied surfaces. The study investigated the application of weld overlay using colomonoy 6 on a plain carbon steel, aimed to create a hard and wear-resistant surface. The overlaying processes were performed using plasma transfer arc welding and gas tungsten arc welding under identical conditions. Microstructural characteristics were examined through optical and electron microscopy, and Phase analysis was performed using X-ray diffraction technique. The wear behavior of the weld overlays was evaluated using pin-on-disc wear testing at three different temperatures: 25 °C, 300 °C, and 600 °C, using an alumina pin. The microstructural investigation revealed the formation of dendritic nickel-rich solid solutions and interdendritic carbide and boride phases within the overlays, contributing to improved hardness and wear properties. Results demonstrated that in both overlaying methods, the wear mechanism at room temperature was mild abrasive, whereas at 600 °C, it was plastic deformation, exhibiting a wear track depth of approximately 33-35 μm, and 50-55 μm, respectively. In both overlayed metals, an approximate Vickers hardness number of 600 was measured a 4-fold increase in hardness of substrate. This finding suggests that factors other than hardness, such as microstructural stability and phase distribution at elevated temperatures, play significant roles in wear performance.